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I'm not super competitive savvy but this is the moveset I use for my Lucario...
Lucario @ ??? (haven't decided yet lol)
4 HP / 252 Atk / 252 Spe
Lonely
Inner Focus
-Swords Dance
-Close Combat
-Crunch
-ExtremeSpeed
He's based off Smogon's "Anti-Lead" moveset, Swords Dance replaced Counter. I use him in the Battle Frontier so I figured Swords Dance would go more nicely... and it's also a little for novelty and is a little easier to apply in-game than Counter.
Not sure what item to give him, though. If I want to buff up with Swords Dance I can't give him a Choice-Item... that alone might make this moveset unsuitable, I dunno. Right now he has a Razor Claw as a filler item, and he does pretty well in the Frontier for me. I'll probably get him a Muscle Band or something eventually.
Ever thought of using the Life Orb?
I'm curious, but what good movests are there for T-tars/Zangooses/and Espeons?